Akechi Mitsuhide — Unlocked by: Clearing Chapter 3, “Battle of Honnoji Post-modification”
Date Masamune — Unlocked by: Clearing Chapter 2, “Battle of Luoyang”
Hattori Hanzo — Unlocked by: Clearing Chapter 3, “Battle of Yohei Seki”
Kunoichi — Unlocked by: Clearing Chapter 1, “Battle of Yi Ling”
Maeda Keiji — Unlocked by: Clearing Chapter 2, “Battle of Luoyang”
Mori Ranmaru — Unlocked by: Clearing Chapter 1, “Battle of Nagashino”
Nohime — Unlocked by: Clearing Chapter 3, “Battle of Honnoji”
Oda Nobunaga — Unlocked by: Clearing Chapter 3, “Battle of Honnoji”
Oichi — Unlocked by: Clearing Chapter 2, “Battle of Xuchang”
Okuni — Unlocked by: Clearing Chapter 3, “Battle of Luo Cheng”
Saika Magoichi — Unlocked by: Clearing Chapter 2, “Battle of Mount Ding Jun Post-modification”
Sanada Yukimura — Unlocked by: Clearing Chapter 1, “Battle of Nagashino”
Takeda Shingen — Unlocked by: Clearing Chapter 3, “Battle of Osaka Castle”
Toyotomi Hideyoshi — Unlocked by: Clearing Chapter 1, “Battle of Nagashino”
Uesugi Kenshin — Unlocked by: Clearing Chapter 3, “Battle of Osaka Castle”
Characters: Samurai 2
Asai Nagamasa — Unlocked by: Clearing Chapter 2, “Battle of Hasedo”
Chosokabe Motochika — Unlocked by: Clearing Chapter 2, “Battle of Liang Zhou”
Fuma Kotaro — Unlocked by: Clearing Chapter 3, “Shou chun Koryaku-sen”
Honda Tadakatsu — Unlocked by: Clearing Chapter 3, “Battle of Yohei Seki”
Ieyasu Tokugawa — Unlocked by: Clearing Chapter 3, “Battle of Chengdu”
Imagawa Yoshimoto — Unlocked by: Clearing Chapter 2, “Battle of Liang Zhou”
Inahime — Unlocked by: Clearing Chapter 3, “Battle of Yi Ling”
Ishida Mitsunari — Unlocked by: Clearing Chapter 3, “Battle of Tong Gate”
Maeda Toshiie — Unlocked by: Clearing Chapter 2, “Battle of Anegawa”
Naoe Kanetsugu — Unlocked by: Clearing Chapter 2, “Battle of Anegawa”
Nene — Unlocked by: Clearing Chapter 2, “Battle of Xuchang”
Sakon Shima — Unlocked by: Clearing Chapter 1, “Battle of Ueda Castle”
Tachibana Ginchiyo — Unlocked by: Clearing Chapter 1, “Battle of Dong Kou”
Yoshihiro Shimazu — Unlocked by: Clearing Chapter 1, “Battle of Odawara Castle”
Characters: Samurai 3
Aya-Gozen — Unlocked by: Clearing Chapter 3, “Battle of Shizugatake”
Hojo Ujiyasu — Unlocked by: Clearing Chapter 3, “Battle of Nagasaka”
Hosokawa Gracia — Unlocked by: Clearing Chapter 3, “Battle of Guang Zhong”
Ishikawa Goemon — Unlocked by: Clearing Chapter 2, “Battle of Kyushu”
Kaihime — Unlocked by: Clearing Chapter 1, “Battle of Odawara Castle”
Kato Kiyomasa — Unlocked by: Clearing Chapter 2, “Battle of Hasedo”
Kuroda Kanbei — Unlocked by: Clearing Chapter 1, “Battle of Dong Kou”
Masanori Fukushima — Unlocked by: Clearing Chapter 1, “Battle of Shou Chun”
Miyamoto Musashi — Unlocked by: Clearing Chapter 1, “Battle of Odawara Castle Post-modification”
Mori Motonari — Unlocked by: Clearing Chapter 2, “Battle of Sekigahara”
Sasaki Kojiro — Unlocked by: Clearing Chapter 2, “Battle of Nan Zhong”
Shibata Katsuie — Unlocked by: Clearing Chapter 2, “Battle of Xuchang”
Tachibana Muneshige — Unlocked by: Clearing Chapter 2, “Battle of Xing Shi”
Takenaka Hanbei — Unlocked by: Starting Character
Characters: Shu
Bao Sanniang — Unlocked by: Clearing Chapter 2, “Battle of Kyushu”
Guan Ping — Unlocked by: Clearing Chapter 3, “Battle of Jie Ting”
Guan Suo — Unlocked by: Clearing Chapter 1, “Battle of Ushizuyama”
Guan Yu — Unlocked by: Clearing Chapter 2, “Battle of Mount Ding Jun”
Huang Zhong — Unlocked by: Clearing Chapter 1, “Battle of Yi Ling Post-modification”
Jiang Wei — Unlocked by: Clearing Chapter 2, “Battle of Xuchang Post-modification”
Liu Bei — Unlocked by: Clearing Chapter 3, “Battle of Chengdu”
Liu-Chan — Unlocked by: Clearing Chapter 2, “Battle of Hasedo”
Ma Chao — Unlocked by: Starting Character
Ma Dai — Unlocked by: Clearing Chapter 1, “Battle of Yi Ling”
Pang Tong — Unlocked by: Clearing Chapter 4, “Battle of Komaki Nagakute”
Wei Yan — Unlocked by: Clearing Chapter 2, “Battle of Nan Zhong”
Xing Cai — Unlocked by: Clearing Chapter 2, “Battle of Xuchang”
Yue Ying — Unlocked by: Clearing Chapter 2, “Tedorigawa Kikousen”
Zhang Fei — Unlocked by: Clearing Chapter 3, “Battle of Yohei Seki”
Zhao Yun — Unlocked by: Clearing Chapter 3, “Battle of Yohei Seki”
Zhuge Liang — Unlocked by: Clearing Chapter 3, “Battle of Chengdu”
Characters: Wei
Cai Wenji — Unlocked by: Clearing Chapter 2, “Battle of Anegawa”
Cao Cao — Unlocked by: Clearing Chapter 3, “Battle of Fancheng”
Cao Pi — Unlocked by: Clearing Chapter 3, “Battle of Hu Lao Gate”
Cao Ren — Unlocked by: Clearing Chapter 2, “Battle of Mount Ding Jun”
Dian Wei — Unlocked by: Clearing Chapter 3, “Battle of Nagasaka Post-modification”
Guo Jia — Unlocked by: Clearing Chapter 3, “Battle of Fancheng Post-modification”
Jia Xu — Unlocked by: Clearing Chapter 1, “Battle of Dong Kou”
Pang De — Unlocked by: Clearing Chapter 1, “Battle of Yi Ling”
Wang Yi — Unlocked by: Clearing Chapter 4, “Battle of Nagashino”
Xiahou Dun — Unlocked by: Clearing Chapter 3, “Battle of Fancheng”
Xiahou Yuan — Unlocked by: Clearing Chapter 1, “Battle of Nan-Jun”
Xu Chu — Unlocked by: Clearing Chapter 3, “Battle of Tong Gate”
Xu Huang — Unlocked by: Clearing Chapter 1, “Battle of Dong Kou”
Zhang He — Unlocked by: Clearing Chapter 2, “Battle of Xuchang”
Zhang Liao — Unlocked by: Clearing Chapter 1, “Battle of Ueda Castle”
Zhen Ji — Unlocked by: Clearing Chapter 3, “Battle of Hu Lao Gate”
Character: Wu
Da Qiao — Unlocked by: Clearing Chapter 3, “Battle of Nagasaka”
Ding Feng — Unlocked by: Clearing Chapter 1, “Battle of Odawara Castle”
Gan Ning — Unlocked by: Clearing Chapter 2, “Battle of Mikatagahara”
Huang Gai — Unlocked by: Clearing Chapter 1, “Battle of Dong Kou”
Lian Shi — Unlocked by: Clearing Chapter 1, “Battle of Nagashino Post-modification”
Ling Tong — Unlocked by: Clearing Chapter 2, “Battle of Tao shui”
Lu Meng — Unlocked by: Clearing Chapter 2, “Battle of Zhang gu tang Post-modification”
Lu Xun — Unlocked by: Clearing Chapter 4, “Battle of Hefei”
Sun Ce — Unlocked by: Clearing Chapter 3, “Battle of Nagasaka”
Sun Jian — Unlocked by: Clearing Chapter 3, “Battle of Honnoji”
Sun Quan — Unlocked by: Clearing Chapter 2, “Battle of Mount Ding Jun”
Sun Shang Xiang — Unlocked by: Clearing Chapter 1, “Battle of Odawara Castle”
Taishi Ci — Unlocked by: Clearing Chapter 1, “Battle of Ueda Castle”
Xiao Qiao — Unlocked by: Clearing Chapter 1, “Battle of Odawara Castle”
Zhou Tai — Unlocked by: Clearing Chapter 1, “Battle of Nagashino”
Zhou Yu — Unlocked by: Clearing Chapter 3, “Battle of Nagasaka”
Deng Ai — Unlocked by: Clearing Chapter 1, “Battle of Dong Kou”
Guo Huai — Unlocked by: Clearing Chapter 1, “Battle of Nagashino”
Sima Shi — Unlocked by: Clearing Chapter 3, “Battle of Tong Gate”
Sima Yi — Unlocked by: Clearing Chapter 3, “Battle of Hu Lao Gate”
Sima Zhao — Unlocked by: Starting Character
Wang Yuanji — Unlocked by: Clearing Chapter 1, “Battle of Ueda Castle”
Xiahou Ba — Unlocked by: Clearing Chapter 2, “Battle of Mount Ding Jun”
Zhong Hui — Unlocked by: Clearing Chapter 4, “Battle of Luoyang”
Zhuge Dan — Unlocked by: Clearing Chapter 1, “Battle of Ueda Castle”
More Characters
Da Ji — Unlocked by: Clearing Chapter 2, “Battle of Sekigahara”
Diao Chan — Unlocked by: Clearing Chapter 3, “Battle of Tong Gate Post-modification”
Dong Zhuo — Unlocked by: Clearing Chapter 3, “Battle of Chengdu”
Fu Xi — Unlocked by: Clearing Chapter 3, “Battle of Honnoji”
Lu Bu — Unlocked by: Clearing Chapter 3, “Battle of Osaka Castle” Play as Diao Chan and meet him before he loses the battle.
Meng Huo — Unlocked by: Clearing Chapter 2, “Battle of Nan Zhong”
Minamoto no Yoshitsune — Unlocked by: Clearing Chapter 1, “Battle of Shou Chun”
Nu Wa — Unlocked by: Clearing Chapter 3, “Battle of Fancheng”
Orochi — Unlocked by: Completing story mode with TRUE ending
Sun Wukong — Unlocked by: Completing story mode with TRUE ending
Taigong Wang — Unlocked by: Clearing Chapter 1, “Battle of Shou Chun”
Taira no Kiyomori — Unlocked by: Completing story mode with TRUE ending
Yuan Shao — Unlocked by: Clearing Chapter 2, “Battle of Jian Ge”
Zhang Jiao — Unlocked by: Clearing Chapter 3, “Battle of Guang Zhong”
Zhu Rong — Unlocked by: Clearing Chapter 2, “Battle of Nan Zhong”
Zuo Ci — Unlocked by: Clearing Chapter 2, “Battle of Anegawa”